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Layered manganese oxide / aniline - o-anisidine copolymer composites Preparation and properties of


n, YANGDong-ya, CA0Guo-rong. , JIANGYan,[link widoczny dla zalogowanych], WEIHua, ZHOUYu-ruing. ,[link widoczny dla zalogowanych], LIUJu-zheng. , ZHANGXu-ping (1.SchoolofChemistryandChemicalEngineering, JiangsuUniversity, Zhenjiang212013, China; 2.FacultyofScience, JiangsuUniversity,[link widoczny dla zalogowanych], Zhenjiang212013, China; 3.SchoolofChemistryandChemicalEngineering, SoutheastUniversity, Nanjing210096, Chinal4.Instituteof0pticalCommunicationEngineering, NanjingUniversity,[link widoczny dla zalogowanych], Nanjing210093, China) Abstract: Theazopolymerbasedonpolyimidwhichused4. 4 'a DiaminodiphenylEther (4,4 'an ODA) 4,4' a (Hexafluor0isopropylidene) diphthalicAnhydride (6FI) A) anddispersedredl (DR1),[link widoczny dla zalogowanych], wassynthesizedwithmaltingopticalwaveguidedevice. Thethermalpropertiesofpolymerwerecharacterizedusingthedifferentialscanningcalorimeter (DSC) andthermalgravimetricanalysis (TGA). TheDSCandTGAexhibitedhighTgandthetemperatureatwhich53, 6masslossoccurredofpolyimidewere223and282 ℃, respectively. Thematerialhasgoodthermalstability. Themeasurementsofrefractiveindex (\a 2.1464 ~ a 3.8857) Xl0 / ℃ and (2.13 ~ 7.44) × 1OI7 / ℃ (complexlight), a 3.8445 × 1O call / ℃ and7.81 × 1O / ℃ (577nm) re-spectively.Theconclusionhadalittlesignificancetodevelopnewthedigitalopticalswitchwithlowdrivingpowerandopticalcommunication.Keywords: azopolymer; thermal-opticcoefficient; volumeexpansioncoefficient

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